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There is a useful diagrammatic representation of this process given here Libby, Anderson and Arnold (1949) were the first to measure the rate of this decay.They found that after 5568 years, half the C14 in the original sample will have decayed and after another 5568 years, half of that remaining material will have decayed, and so on (see figure 1 below).As 14C decays it emits a weak beta particle (b ), or electron, which possesses an average energy of 160ke V.The decay can be shown: Thus, the 14C decays back to 14N.They exist in equilibrium with the C14 concentration of the atmosphere, that is, the numbers of C14 atoms and non-radioactive carbon atoms stays approximately the same over time.

Libby of the University of Chicago in immediate post-WW2 years.

There is a quantitative relationship between the decay of 14C and the production of a beta particle. That is, the probability of decay for an atom of 14C in a discrete sample is constant, thereby requiring the application of statistical methods for the analysis of counting data.

It follows from this that any material which is composed of carbon may be dated.

The 14C formed is rapidly oxidised to 14CO2 and enters the earth's plant and animal lifeways through photosynthesis and the food chain.

The rapidity of the dispersal of C14 into the atmosphere has been demonstrated by measurements of radioactive carbon produced from thermonuclear bomb testing.